Enhanced Water Splitting Performance of CoZnCr@MXene in Alkaline Seawater and Anion Exchange Membrane Electrolysis
Payal Chauhan a, Bing Wu a, Jan Plutnar a, Jakub Regner a, Alkesh Patel a, Martin Loula b, Zdenek Sofer a
a Department of Inorganic Chemistry, University of Chemistry and Technology Prague, Technická 5, Prague 6, 16628 Czech Republic
b Institute of Organic Chemistry and Biochemistry, Czech Academy of Sciences, Flemingovo nám. 2, 166 10 Prague 6, Czech Republic
Proceedings of The Future of Hydrogen: Science, Applications and Energy Transition (H2Future25)
Production
Ibiza, Spain, 2025 May 5th - 7th
Organizers: Teresa Andreu, Bahareh Khezri and Jose Mata
Contributed talk, Payal Chauhan, presentation 005
Publication date: 27th March 2025

Developing effective electrocatalysts for large-scale seawater splitting that can prevent anodic corrosion while efficiently driving oxygen evolution is a major challenge. Surface engineering plays a pivotal role in advancing electrocatalysts, bridging the gap between basic research and the real-world needs of industrial water-splitting technologies. In this study, we introduce the CoZnCr@MXene heterostructure, which achieves a remarkable cell voltage of 1.55 V at a current density of 50 mA cm⁻², surpassing the performance of RuO₂ in alkaline seawater electrolytes. This outstanding performance is attributed to the combined benefits of compositional optimization, surface modification, and the integration of conductive supports, all of which contribute to significant reductions in overpotentials for both the oxygen evolution reaction (OER) and the hydrogen evolution reaction (HER). The CoZnCr@MXene catalyst shows exceptional stability and selective oxidation in alkaline seawater, with the MXene incorporation effectively preventing chloride-induced corrosion and improving charge transfer efficiency. Additionally, when used in an anion exchange membrane electrolyzer, the CoZnCr@MXene catalyst delivers a current density of 500 mA cm⁻² at an operating voltage of 1.72 V at 60 °C, achieving a cell efficiency of 77.8%. This work marks a significant step forward in the development of durable, noble-metal-free electrodes for industrial-scale alkaline seawater electrolysis.

P.C. acknowledges the financial support from the European Union's Horizon Europe research and innovation program under the Marie Skłodowska - Curie grant agreement No. 101130803.

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