Micro-Patterning of Perovskite Nanocrystal Films Using Laser Writer Lithography
Andreas Manoli a, Theodosia Giamouki a, Modestos Athanasiou a, Maryna Bodnarchuk b c, Maksym Kovalenko b c, Grigorios Itskos a
a Department of Physics, Experimental Condensed Matter Physics Laboratory, University of Cyprus, Kallipoleos, 75, Nicosia, Cyprus
b Institute of Inorganic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, CH-8093 Zürich, Switzerland
c Laboratory for Thin Films and Photovoltaics, Empa – Swiss Federal Laboratories for Materials Science and Technology, Überlandstrasse 129, CH-8600 Dübendorf, Switzerland.
Proceedings of Emerging Light Emitting Materials 2024 (EMLEM24)
La Canea, Greece, 2024 October 16th - 18th
Organizers: Grigorios Itskos, Sohee Jeong and Jacky Even
Poster, Andreas Manoli, 030
Publication date: 13th July 2024

Optical lithography has been the key enabler for scaling feature sizes of integrated circuits, allowing the exponential growth of the semiconductor industry. Traditional photolithography involves the use of a photomask and a mask aligner to transfer the desired pattern onto a wafer. An alternative method is maskless lithography, in which the pattern is directly exposed onto the substrate surface using a light sensitizer such as a laser. For many applications this is preferred as it allows to circumvent the lengthy process of designing and manufacturing a photomask to transfer the desired pattern onto the wafer.   

Herein we develop a custom-made laser writer lithography system based on a motorized micro-photoluminescence setup with which various micro – patterns, such us arrays of pixels, dots, waveguides etc. are transferred onto CsPbBr3 nanocrystal (NC) films deposited on silicon substrates. The structural and optical properties of the patterned NCs are investigated with a combination of atomic force microscopy (AFM), near-field scanning optical microscopy (NSOM) and hyperspectral photoluminescence mapping experiments. Such patterned NC solids can evolve into functional building blocks for solution-processed micro-scale photonic circuits and devices.

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