Manganese Hybrid Halides for High-resolution X-ray Imaging Screen
Alaa Almushaikeh a, Omar F. Mohammed a
a King Abdullah University of Science and Technology (KAUST), Advanced Membranes and Porous Materials Center, Division of Physical Science and Engineering, Thuwal, 23955, Saudi Arabia
Proceedings of Emerging Light Emitting Materials 2024 (EMLEM24)
La Canea, Greece, 2024 October 16th - 18th
Organizers: Grigorios Itskos, Sohee Jeong and Jacky Even
Oral, Alaa Almushaikeh, presentation 014
DOI: https://doi.org/10.29363/nanoge.emlem.2024.014
Publication date: 13th July 2024

X-ray imaging scintillators are essential in various applications, including medical imaging and security checks. There is a pressing need to develop innovative, environmentally friendly scintillation materials with robust screen fabrication to meet industrial demand and minimize X-ray exposure risks. In this work, we focus on the synthesis and screen fabrication of zero-dimensional manganese hybrid halides with near-unity PLQY emission. We also explored the practical application of Mn(II)-based imaging scintillators for everyday X-ray imaging. Notably, the manganese(II) hybrid bromide scintillators demonstrated an ultrahigh resolution of up to 20.8 lp/mm, surpassing both conventional scintillators and recent alternatives. Additionally, these large-area imaging scintillators achieved a high light yield of 20,000 photons/MeV and an impressively low detection limit of just 180 nGy/s, which is 30 times lower than the typical dose required for medical radiography diagnosis (5.5 µGy/s). Finally, we present compelling evidence of the practicality of using high-resolution Mn(II) hybrid bromide scintillators for X-ray imaging applications.

The authors acknowledge the support of King Abdullah University of Science and Technology (KAUST).

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