Improvements of perovskite nanocrystals for light-emitting applications
Andrey Rogach a
a Department of Materials Science and Engineering, City University of Hong Kong, Hong Kong SAR, P.R. China
Proceedings of International Conference on Emerging Light Emitting Materials (EMLEM23)
Peyia, Cyprus, 2023 November 13th - 15th
Organizers: Grigorios Itskos, Maksym Kovalenko and Maryna Bodnarchuk
Invited Speaker, Andrey Rogach, presentation 007
DOI: https://doi.org/10.29363/nanoge.emlem.2023.007
Publication date: 18th August 2023

Chemically synthesized metal halide perovskite nanocrystals have recently emerged as a new class of efficient light emitting materials which are particularly promising for development of light-emitting diodes (LEDs). Stability of perovskite-based LEDs is still an issue, which can be partially mitigated by proper interface design, such as the use of inter-layer amine terminated carbon dots. As for many other colloidal nanocrystals, proper surface passivation is a key to ensure high colloidal stability and processability of perovskites; this can be achieved by employment of multi-amine chelating ligands. We also show how water-stable perovskite nanocrystals with a mixed fluoropolymer shell can be applied for optical temperature sensing. The use of the lead-based metal halide perovskites is also considered as an issue because of the toxicity concerns related to the lead component. To avoid using lead in light-emitting perovskites, co-doping of cerium and bismuth, as well as tellurium and bismuth into lead-free double perovskite nanocrystals is a useful strategy resulting in their improved photoluminescence efficiency.

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