Single particle optical characterization of silica nanospheres containing lead halide perovskite emitters
Susan Rigter a b, Julia van der Burgt a, Peter Schall b, Erik Garnett a b
a Center for Nanophotonics, AMOLF, Amsterdam, The Netherlands, Science Park 104, Amsterdam, Netherlands
b Institute of Physics, University of Amsterdam, Science Park 904, 1098 XH Amsterdam, The Netherlands, Netherlands
Proceedings of International Conference on Emerging Light Emitting Materials (EMLEM22)
Aspects of Emergent Light Emitters:
Limasol, Cyprus, 2022 October 3rd - 5th
Organizers: Maksym Kovalenko, Maryna Bodnarchuk and Grigorios Itskos
Oral, Susan Rigter, presentation 039
DOI: https://doi.org/10.29363/nanoge.emlem.2022.039
Publication date: 15th July 2022

Cesium lead halide perovskites are great candidates for lighting applications such as LEDs or screens, due to their bright photoluminescence with narrow bandwidth, originating from a tunable band gap. However, before applications can be realized, important challenges that are inherent to the materials need to be addressed. Lead halide perovskites are unstable under operation conditions - they degrade easily, for example upon contact with water, heat, or strong irradiation. Encapsulating perovskites in silica spheres stabilizes the perovskite emitters, protecting them from these influences. By controlling the shape and size of the silica, the material can be patterned and the optical properties can be tuned. In this talk, I will show the enhanced stability of perovskite emitters in silica spheres. Futhermore, I will provide an optical characterization of individual perovskite-filled silica spheres in the size range in the order of hundreds of nanometers, and methods to pattern these spheres for applications.

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