Near-Infrared Light-emitting diodes based on RoHS complaint colloidal semiconductor quantum dots
Manuela De Franco a c, Houman Bahmani Jalali a d, Dongxu Zhu d, Luca De Trizio d, Mirko Prato b, Liberato Manna d, Francesco Di stasio a
a Photonic Nanomaterials group, Istituto Italiano di Tecnologia, Via Morego 30, 16163 Genova, Italy
b Materials Characterization Facility, Istituto Italiano di Tecnologia, Genoa, Italy
c Dipartimento di Chimica e Chimica Industriale, Università degli Studi di Genova, Via Dodecaneso, 31, 16146, Genova, Italy​
d Nanochemistry, Istituto Italiano di Tecnologia (IIT), via Morego 30, 16163 Genova, Italy.​
Proceedings of International Conference on Emerging Light Emitting Materials (EMLEM22)
Materials for next generation LEDs and lasers:
Limasol, Cyprus, 2022 October 3rd - 5th
Organizers: Maksym Kovalenko, Maryna Bodnarchuk and Grigorios Itskos
Oral, Francesco Di stasio, presentation 014
DOI: https://doi.org/10.29363/nanoge.emlem.2022.014
Publication date: 15th July 2022

Near-infrared Light-emitting diodes (NIR-LEDs) based on colloidal semiconductor quantum dots (QDs) are of interest for a variety of optoelectronic applications such as hyperspectral and biomedical imaging, night vision and telecommunication systems. Importantly, all efficient NIR-LEDs based on QDs employ toxic heavy metals compositions [1] while The European Union’s “Restriction of Hazardous Substances” (RoHS) directive limits the use of such compounds. Colloidal indium arsenide QDs are emerging as a promising candidate for NIR applications[2] thanks to their low toxicity and recent progresses in material synthesis leading to stable and highly efficient QDs [3]. Here, we fabricated NIR-LEDs emitting in the range of 800-1000 nm based on heavy metal-free efficient InAs/ZnSe core-shell QDs (PLQY >40%) [3]. The resulting external quantum efficiency of NIR-LEDs benefited from nanoengineering at both material and device levels. This study demonstrates that InAs based QDs are a promising nanomaterial for the fabrication of optoelectronic devices operating in the NIR.

We acknowledge support from the European research council project NANOLED (ERC-StG 851794) and the MSCA individual fellowship INFLED (101024823). This work was performed in part in the Clean Room Facility of the Istituto Italiano di Tecnologia; its support and resources are here acknowledge.

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