Molecular Passivation of MoO3: Band Alignment and Protection of Charge Transport Layers in Vacuum-Deposited Perovskite Solar Cells
a Universidad de Valencia - ICMol (Institute of Molecular Science), Catedrático José Beltrán Martinez 2, Paterna, Spain
b Institute of Materials Science of the University of Valencia (ICMUV), Spain
Online Meetups
Proceedings of Online Meetup: Origins of Electronic Defects in Halide Perovskites (EDHP)
Proceedings of Online Meetup: Origins of Electronic Defects in Halide Perovskites (EDHP)
Online, Spain, 2020 April 2nd - 2nd
Poster, Daniel Pérez-del-Rey, 012
Publication date: 1st April 2020
Publication date: 1st April 2020
ePoster:
Vacuum deposition of perovskite solar cells can achieve efficiencies rivaling solution-based methods and allows for more complex device stacks. MoO3 has been used to enhance carrier extraction to the transparent bottom electrode in a p-i-n configuration; here, we show that by inserting an molecular interlayer with a lone pair nitrogen atom and low ionization potential, it can also be used on the top of a perovskite absorber in a n-i-p configuration. This strategy enables the first vacuum-deposited perovskite solar cells with metal oxides as charge transporting layers for both electrons and holes, leading to power conversion efficiency >19%.
© FUNDACIO DE LA COMUNITAT VALENCIANA SCITO