Proceedings of International Conference Asia-Pacific Hybrid and Organic Photovoltaics 2018 (AP-HOPV18)
Publication date: 27th October 2017
Despite tremendous efforts to enhance the performance of polymer- and perovskite-based solar cells (PSCs and PeSCs), considerable energy loss is still caused by the non-radiative recombination of charges or charge-transfer excitons as a result of trapping sites and insufficient internal electric fields (Ein). Thus, a strong Ein across the photoactive layer is required for efficient charge extraction at each electrode. Here, we report a universal method of ensuring a larger Ein in both PSCs and PeSCs through the incorporation of a pair of strong electric dipole layers (EDLs) based on conjugated polyelectrolytes for both anode and cathode. The Ein that develops between the EDLs is significantly intensified, and the sweep-out time of the photo-generated charges is shortened by ~ 50%. Our approach is generally applicable to various donor polymers and perovskite systems, and it results in an enhancement of the power conversion efficiencies (PCEs) of both PSCs and PeSCs by > 15% compared with conventional devices using typical charge transport layers (CTLs) such as metal oxides and/or conducting polymers.