Proceedings of International Conference Asia-Pacific Hybrid and Organic Photovoltaics 2018 (AP-HOPV18)
Publication date: 27th October 2017
NiO-based inverted perovskite solar cells (PSCs) show great potential due to the good stability and hysteresis-free properties. However, the photovoltaic performance of the devices is significantly dependent on oxidation state of Ni, oxygen vacancy and electrical properties of NiO films. Here, we have investigated effects of annealing atmospheres (including air, O2, N2 and Ar) of NiO films. We have found that photovoltaic performance of the devices is strongly dependent on annealing atmospheres of NiO thin films. Under air and O2 atmosphere, the formation of the Ni3+ vacancies enhances the conductivity which promotes the charge collection leading to a better photovoltaic performance. In contrast, the devices using NiO films annealed in inert or reduction atmospheres such as Ar or N2 show much lower efficiency because of the poor conductivity. The best photovoltaic performance is achieved under air atmosphere with an efficiency of 15.05% which is higher than annealed in O2, N2 and Ar conditions.