Enhanced Efficiency of Hole-conductor Free Perovskite Solar Cells with carbon electrode
Kwan-Woo Ko a b, Sungjun Hong a, Soon-Gil Yoon b, Chi-Hwan Han a
a Korea Institute of Energy Research, 152, Gajeong-ro, Yuseong-gu, Daejeon, 305, Korea, Republic of
b Chungnam National University
Asia-Pacific International Conference on Perovskite, Organic Photovoltaics and Optoelectronics
Proceedings of International Conference Asia-Pacific Hybrid and Organic Photovoltaics 2018 (AP-HOPV18)
Kitakyūshū-shi, Japan, 2018 January 28th - 30th
Organizers: Shuzi Hayase, Juan Bisquert and Hiroshi Segawa
Poster, Kwan-Woo Ko, 097
Publication date: 27th October 2017

 Organometal halide perovskite solar cells has attracted much attention in the scientific community. Methylammonium lead halide (CH3NH3PbX3,X = I or Br or Cl) perovskites have a large light absorption coefficient, long carrier diffusion length and long range charge carrier lifetime. In general, perovskite solar cells consisted of perovskite layer as a light-absorbing layer sandwiched between the electron transport layer (ETL) (eg. TiO2 or ZnO) and hole transport layer (HTL) (eg. Spiro-MeOTAD or PTAA). Novel metals such as Au or Ag were used as a metal counter electrode. Such materials are costly besides having extreme limitation of enduring stability, thereby impeding the future perovskite solar cells’ commercialization. To obtain solutions over these issues, various research teams have offered results acquired from hole-conductor free perovskites through having the both novel and HTL materials replaced with affordable carbon materials.

 We fabricated hole-conductor free perovskite solar cells using carbon materials as counter electrode. In this structure, interface engineering between the perovskite and carbon counter electrode plays a critical role in determining an overall performance of device. Keeping this aspect in mind, we focused on improving the morphology of perovskite film by changing the solubility factor of lead salt in commonly used organic solvents along with a small amount of water additive. The function of water additive is to increase solubility of lead precursor and control the grain growth of perovskite film. We have investigated effects of water additive on perovskite crystallization, morphology of perovskite film and device performance. We have achieved a power conversion efficiency of 8.165% which is among the highest for hole-conductor free perovskite solar cells.

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