Proceedings of International Conference Asia-Pacific Hybrid and Organic Photovoltaics 2018 (AP-HOPV18)
Publication date: 27th October 2017
Recently, organic–inorganic hybrid perovskites have attracted considerable attention as possible next-generation thin-film solar cells because of their advantages such as low-cost of precursors, long exciton diffusion length etc. Although the most efficient perovskite solar cells (PSCs) have usually employed hole transporting materials (HTMs), which play a key role in hole transportation and retardation of charge recombination, improvement in the PSC photovoltaic performance mainly relies on optimizing various device fabricating methods, elaborate engineering of perovskite morphology, and composition. To further improve the efficiency and stability of PSC, efforts have been made to research on appropriate HTMs, especially dopant-free HTMs. Herein we demonstrate the improvement in efficiency and stability of PSCs utilizing non-peripherally substituted octapentyl phthalocyanine (C5PcH2) as dopant-free HTM layers with thermal annealing. By using dopant-free C5PcH2 in combination with CH3NH3PbI3, a final device efficiency of 12.2% was achieved by annealing at 130 ºC for 10 min. Furthermore, to verify the stability enhancement of the dopant-free C5PcH2 HTM, we investigated three employed HTMs, including the free-dopant C5PcH2, poly(3-hexylthiophene) with Li-bis(trifluoromethanesulfonyl) imide, and poly-triarylamine with Li-bis(trifluoromethanesulfonyl) imide, and subject CH3NH3PbI3 perovskite thin films coated with these HTMs to dark air with high humidity of 90%. The results indicated that decomposing of CH3NH3PbI3 perovskite to PbI2 through the hydration processes was decelerated by coating the free-dopant C5PcH2 HTM layer [1, 2].
[1] Quang-Duy Dao, Ryotaro Tsuji, Akihiko Fujii, and Masanori Ozaki, Org. Electron. 43 (2017) 229-234.
[2] Quang-Duy Dao, Akihiko Fujii, Ryotaro Tsuji, Yuko Takeoka, and Masanori Ozaki, Org. Electron. 43 (2017) 156-161.