Proceedings of International Conference Asia-Pacific Hybrid and Organic Photovoltaics (AP-HOPV17)
Publication date: 7th November 2016
Inorganic-organic hybrid perovskite solar cells (PSCs) have shown dramatic achievements in certified power conversion efficiency (PCE) surpassing 20% in the last four years. However, there remains significant concern on the stability of the PSCs in environmental conditions that must be addressed prior to commercialisation, albeit the meteoric rise of the photovoltaic performance. We demonstrate thermal stability of the perovskite solar cells with high efficiency using copper thiocyanate (CuSCN) as an inorganic hole conductor, which possesses highly stable crystalline structure and robustness even at high temperature (200 °C). The efficient charge separation from perovskite layer into CuSCN has been evidenced by steady-state and time-resolved photoluminescence (PL) measurements with time-correlated single photon counting (TCSPC). The perovskite solar cells with the CuSCN exhibit a maximum 18.0% efficiency comparable to spiro-OMeTAD-based perovskite solar cells (18.4%). The PSCs fabricated with spiro-OMeTAD dropped to 25% of initial PCE after annealing for 2 h at 125 °C in ambient conditions. However, CuSCN-based PSCs were found to retain approximately 60% of initial value, indicating superior thermal stability to spiro-OMeTAD-based PSCs under identical testing conditions. This work demonstrates that high efficiency and improved thermal stability are simultaneously achieved from CuSCN used as an inorganic hole conductor in PSCs.