High performance and stable pseudohalide perovskite nanowires photodetector
Ivy M. Asuo a b, Dawit Gedamu a, Ibrahima Ka a, Luis Felipe Gerlein a, Alain Pignolet b, Sylvain G. Cloutier a, Riad Nechache a
a Département de Génie Électrique, École de Technologie Supérieure, Montreal, CA, Rue Notre-Dame Ouest, 1100, Montréal, Canada
b INRS, Centre for Energy, Materials and Telecommunications, Boulevard Lionel-Boulet, 1650, Varennes, Canada
NIPHO
Proceedings of International Conference on Perovskite Thin Film Photovoltaics, Photonics and Optoelectronics (ABXPV18PEROPTO)
Perovskite Photonics and Optoelectronics (PEROPTO18). 1st March
Rennes, France, 2018 February 27th - March 1st
Organizers: Jacky Even and Sam Stranks
Oral, Ivy M. Asuo, presentation 019
DOI: https://doi.org/10.29363/nanoge.abxpvperopto.2018.019
Publication date: 11th December 2017

High-speed photodetectors are in high demand in many fields including imaging, optical communications, chemical species detection, and other types of optical instrumentation. Mostly, these photodetectors use silicon or semiconductor alloys to build devices that require costly fabrication methods. Recently, organometal halide perovskites have demonstrated outstanding optoelectronic properties such as tunable optical properties, high charge mobility, and long charge diffusion length. In the work, we report a stable, reproducible and reliable pseudohalide perovskite nanowire network based photodetector with superior photodetection performance. The perovskite nanowire networks are deposited onto micropatterned substrates under ambient conditions of relative humidity (RH), higher than 50 % through a two-step spin coating method. Because of the 1D perovskite structure, our devices require no charge extractors which is advantageous for low-cost fabrication and processing simplicity. The photoresponse measurements indicate broad spectral response from 300 to 850 nm, high spectral responsivity, time response and photocurrent. This results indicate that photocurrent generation is due to the charge transfer within the nanowire networks and present a simple, fast and low-cost solution fabrication technique of perovskite nanowire-based photodetectors in ambient air.

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